The 50p coin bears the inscription “Peace, prosperity and friendship with all nations” and the date of January 31.
Mr Javid ordered production of the coins when the UK was first set to leave the EU on the original 31 October departure date.
However, Brexit delays meant a million coins had to be melted down and the metal put aside until a new exit date was confirmed.
Mr Javid said: “Leaving the European Union is a turning point in our history and this coin marks the beginning of this new chapter.”
About three million Brexit coins will enter circulation in the UK from Friday, with a further seven million to be added later in the year.
Mr Javid, who is also Master of the Mint, was given the first batch of coins and will present one to Prime Minister Boris Johnson this week.
As part of the celebrations, the Royal Mint will open its doors for 24 hours on Brexit Day to let people strike their own commemorative coins.
The coin already looks set to be popular with Brexit supporters, with more than 13,000 people registering their interest in buying a commemorative version of the coin.
The European Parliament is expected to approve the Withdrawal Agreement on Wednesday, after Mr Johnson signed the treaty paving the way for the UK to leave on Friday.
The coin is the latest in a series of celebrations for Brexit Day.
The government is currently in talks with Royal Mail bosses over issuing special stamps in time to commemorate Brexit.
It is understood the Prime Minister has stepped in to make a formal request to the postage giant, with one minister dubbing the advances “very positive”.
The Royal Mail had originally opposed the move, insisting that the stamps would breach its “strict political neutrality”.
They could go on sale in January 2021, marking an end to the 11 month-long transition period.
Lord Heseltine has accused Boris Johnson of trying to “rub the noses of Remainers in their defeat” over the government’s plan to commemorate Brexit on January 31.
Union Jacks will line Parliament and the Mall and government buildings will, as reported by the Guardian, be lit up red, white and blue.
A countdown clock will also be projected onto Downing Street.
The Brexit Party will sound its own Big Ben bongs after the House of Commons Commission ruled out ringing the iconic bells on Friday.
It was revealed it would cost £500,000 to do so — a massive rise from the original estimate of £120,000.
More than £270,000 was raised by members of the public to pay for the bells to ring.
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